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Atmospheric corrosion of stainless steels


Stainless steel against internal and external atmospheric corrosion

Introduction



Atmospheric corrosion of stainless steel is not a single form of corrosion, but a collective term to denote the corrosion of surfaces in the atmosphere.
 
It can be indoors or outdoors. Corrosion of stainless steels is most often induced by halides and chlorides due to their abundance in our environment, for example coastal and marine environments.
 
When stainless steel is exposed to an aggressive atmosphere, it mainly stains. But it can also be attacked by localized corrosion, particularly at high chloride levels. It should be noted that discoloration of stainless steel is not automatically the result of atmospheric corrosion of the stainless steel, i.e. it may be discoloration from foreign dirt or rust that is in contact with the stainless steel but does not actually affect it.
 
There are two large areas of application where the application of corrosion knowledge is needed, in the architectural and structural use of stainless steel. Surface appearance is much more important for architectural use, while surface corrosion attack can be neglected in structural applications. Huge possibilities are offered for the use of stainless steels in these areas. Long-term durability and very low metal ion dissolution pairs make stainless steels a very environmentally friendly choice, with low life cycle costs.
 
Atmospheric Corrosion Classification
 
Traditionally, environments have been divided into four different categories: rural, urban, industrial, and marine. In general, corrosivity decreases in the order: industrial, marine, urban and finally rural. However, this classification is not self-evident, for example, an urban environment can be more aggressive than a marine one. Industrial emissions have been regulated of late, resulting in industrial environments with lower corrosivity.
  



Alacer Mas, Atmospheric corrosion of stainless steels
Clasificación de Ambientes UNE EN ISO 12944
Categoría de la corrosividadCategoría de la corrosividadINTERIOREXTERIORCalidades acero inoxidable adecuado
C1Muy BajaEdificios con calefacción con atmósferas limpias. Ejemplo: escuelas, hoteles, tiendas, oficinas430, 444, 304, 201 y aleaciones duplex
C2BajaEdificios sin calefacción donde pueda aparecer condensación; Ejemplo: almacenes, pabellones deportivos.Atmósferas con bajos niveles de contaminación. Áreas rurales en su mayor parte.430, 444, 304, 201 y aleaciones duplex
C3MediaNaves de producción con elevada humedad y algo de contaminación. Ejemplo, planta de producción de alimentos, lavanderías, plantas cerveceras, plantas lácteas.Atmósferas urbanas e industriales, con moderada contaminación de dióxido de azufre. Áreas costeras con baja salinidad. 444, 304, 316 y aleaciones duplex
C4AltaPlantas químicas, piscinas, astilleros costeros (limpieza por chorreado, laboratorios, mataderos) Áreas industriales y costeras con salinidad moderada. Zonas a más de 3 km del litoral marino.316, 317, 904L y aleaciones duplex
C5-MMuy AltaEdificios o zonas con condensación permanente o elevada contaminación.Áreas industriales con elevada humedad y con atmósfera agresiva. 316, 317, 904L y aleaciones duplex
C5-IMuy AltaEdificios o zonas con condensación permanente o elevada contaminación.Áreas costeras y marítimas con elevada salinidad316, 317, 904L y aleaciones duplex